Key Concepts
An oxidation number (oxidation state) is the charge an atom would carry if the molecule or ion were completely ionic.
Rules for Assigning Oxidation
Numbers
- Fluorine is assigned an oxidation number of -1 in compounds
HF oxidation number of fluorine = -1 - Oxygen is assigned an oxidation number of -2 in compounds
H2O oxidation number of oxygen is -2 Except
- Peroxides: oxidation number of oxygen is -1
H2O2 oxidation number of oxygen is -1 - Superoxides: oxidation number of oxygen is -½
KO2 oxidation number of oxygen is ½ - Oxygen fluorides: OF2 oxidation number of oxygen is +2
O2F2 oxidation number of oxygen is +1
- Hydrogen is assigned an oxidation of +1 in compounds
HCl oxidation number of hydrogen is +1 - Group I elements (Alkali Metals) are assigned an oxidation number of +1 in compounds
NaNO3 oxidation number of sodium is +1 - Group II elements (Alkaline-earth metals) are assigned an oxidation number of +2 in compounds
MgBr2 oxidation number of magnesium is +2 - An atom of any element in the free state has an oxidation number of 0
S8 oxidation number of each sulfur atom is 0 - Any monatomic ion has an oxidation number equal to its charge
H- oxidation number of hydrogen is -1 - The sum of the oxidation numbers of all the atoms in a formula equals the electrical charge shown with the formula
- The sum of the oxidation numbers of all the atoms shown in a formula of a compound is 0
CO2: let x be the unknown oxidation number of carbon
0 = x + (2 x -2)
So x (oxidation number of C) = 0 + 4 = +4 - The sum of the oxidation numbers of all the atoms shown in the formula for a polyatomic ion or complex ion equals the electrical charge on the ion
Cr2O72-: let y = unknown oxidation number of chromium
-2 = 2y + (7 x -2)
2y = -2 + 14
2y = +12
y (oxidation number of Cr) = 12 ÷ 2 = +6
rained @ 12:13 AM
Transition metals!
What are they?
The 38 elements in between group II and group III of the periodic table are called transition metals.The name 'transition' derives from their position in the periodic table, as they act as a transition ['bridge'] between the group II and group III elements.
Uses of transition metals...:)
Some transition metals have several uses, especially for iron and copper. Transition metals also often form important alloys like iron in steel, zinc & copper in brass.
Transition metals are good catalysts for particular reactions.
[Note: Catalysts are substances that can be used to change the rate of a reaction.They are usually used to speed up the rate of a reaction. The catalyst itself is not involved in the reaction itself, so it is not changed or used up during the reaction.It stays in its original form even after the reaction is complete! :D]
The bonding of atoms in transition metals is relatively strong.As a result, they are strong metals with high boili
ng and melting points as well as high densities.They also have many electrons to carry energy, thus are effective in conducting electricity
. Many of the transition metals are not very reactive to water or oxygen, but when they form salt compounds, the resulting substance tens to be coloured.For example, cobalt chloride is blue and titanium chloride is purple.
[THEREFORE THEY ARE VERY COLOURFUL METALS!!! YAY! :DDD]
References~!
http://www.ehow.com/about_5366616_uses-transition-metals.html
http://www.gcsescience.com/pt21.htm
http://en.wikipedia.org/wiki/Transition_metal
Labels: catalysts, Transition metals
rained @ 1:08 AM

Hydrogen
Bomb
The Hydrogen bomb works on a physical principle known as nuclear fusion. In nuclear fusion, the nuclei of atoms join together, or fuse to form a heavier nucleus. This happens only under very hot conditions. The explosion of an atomic bomb attached to a hydrogen bomb provides the heat to start the fusion.Hydrogen nuclei fuse to form helium and as this happens, huge amounts of energy are released from the hydrogen nuclei, producing a huge explosion.
Fusion releases energy due to the overall loss in mass. If you add up the masses of the particles which go into a fusion reaction, and you add up the masses of the particles which come out, there is frequently a difference. According to Einstein's famous law relating energy and mass, the "mass difference" can take the form of energy.
Fusion reactions involving nuclei lighter than iron typically release energy, but fusion reactions involving nuclei heavier than iron typically absorb energy. The amount of energy released depends on the specifics of the reaction. The reaction used in the hydrogen bomb, though, produces one of the greatest changes in mass.
The hydrogen bomb is thousands of times more powerful than an atomic bomb. There have not been any hydrogen bombs used in warfare, however there have been hydrogen bomb tests. Most of these tests are done underwater due to risk of destruction. To give you an idea of how strong the H-bomb is, think about this. This atomic bomb dropped on Hiroshima, Japan which killed over 140,000 people had the power of 13 kilotons. A common hydrogen bomb has the power of up to 10 megatons. All the explosions in World War II totalled "only" 2 megatons -- 20% of the power of ONE common hydrogen bomb.
http://www.cartage.org.lb/en/themes/sciences/Physics/NuclearPhysics/Applications/NuclearWeapons/NuclearWeapons.htm
rained @ 6:50 AM
Molecular Orbital Theory
When simple bonding occurs between two atoms, the pair of electrons forming the bond occupies an MO that is a combination of the wave functions of the atomic orbitals of the two atoms involved.
When atoms combine to form a molecule, the number of orbitals in the molecule equals the number of orbitals in the combining atoms. When two very simple atoms, each with one atomic orbital, are combined, two molecular orbitals are formed. One is a bonding orbital, lower in energy than the atomic orbitals, and derived from their sum. It is called sigma. The other is an antibonding orbital, higher in energy than the atomic orbitals, and resulting from their difference.
www.chemistryexplained.com
rained @ 6:35 AM

Dispersion of white light
Sunlight is actually made up of seven different colours although it appears white.
Light can be dispersed using a glass prism. When light shines through a glass prism, the light leaves the prism and disperses into seven colours.The seven colours are red, orange, yellow, green, blue, indigo and violet.
The colour that bends the least is red, and the most violet.This is because red travels the fastest. When light passes throught the prism, the seven colours are dispersed and they travel at different rates.
rained @ 1:16 AM

Why can't the button on the lift work if something is covering your finger(eg. gloves/plaster)?
I think its because of the material of the fabric that causes you to be unable to press the button..Or maybe to press the button it needs to sense heat before it lights up and everything.And if you wear gloves/plasters,the fabric 'blocks' or absorbs the heat and therefore no heat is sensed at the button.


Why does ice 'stick' to your fingers when you take it out of the refridgerator?
First,we have to look at the formation of ice.Ice is the solid state of water,so we look at the formation of water.
Water (H2O) is made up of two molecules of hydrogen and one molecule of oxygen. But oxygen has the two extra pairs of electrons which are known as lone pairs.Every molecule in the water is attached with the nearby molecule through hydrogen bonding.When water is in liquid state every molecule changes its interaction and makes new connections with new molecules which results in water flow. However in its solid state(ice) it cannot break old connections and form new ones.Now the molecules are not in the condition to change their interactions so they remain in one place forming a three dimensional hydrogen bonding.

On the surface of ice some oxygen atoms and hydrogen atoms are left facing outwards which causes them not to connect with the other molecules to form hydrogen bonds. So they are looking for a partner to form the bond.When a surface that is able to form this bond comes in contact with the ice surface it will stick to that, like our skin. Our skin has high moisture content and very appropriate to form the bond with these atoms that is why it sticks to your skin when you touch it.
http://www.letusfindout.com/why-does-ice-stick-to-your-skin/
rained @ 2:18 AM
Are there other versions of the periodic table?Yes!For example,this Chinese one..surprised?Anyway,how do they translate the names of the elements into chinese?Some of the names are so,how do you describe it,'chim'?

Why do we use symbols in the periodic table?
It is to enable everybody,regardless of their language,to understand as symbols are a universal language.
rained @ 6:04 AM

Compounds
Is a substance of 2 or more elements chemically combined.
A chemical reaction takes place when it is formed.
Energy in the form of light and heat are often taken in or given out during the chemical reaction.
When two elements are chemically 'combined together',it becomes a new substance.
It has properties that are different from its consttuent elements by chemical methods.
The different constituent elements are combined in fixed proportions.
rained @ 5:57 AM

ELEMENTS
They are the basic unit of all matter
An element is a substance that cannot be broken down into 2 or more simper substances by any
chemical method
There are 110 elements found on earth till now.
MIXTURES
Substances made up of two or more elements and/or compounds.
The constituents of a mixture are not chemically combined
No chemical reaction occurs when a mixture is formed
It has properties that are similar to its constituent elements that make it up
can be separated into its constituent elements without using any chemical methods.The different contsituent elements are mixed in varied proportions.
Energy in the form of light or heat is not required or given out during mixing.
rained @ 5:00 AM

Overnight, Alaska's Redoubt volcano erupted with five large explosions. The National Weather Service has issued an Ashfall Advisory, with light ashfall already reported in some regions. Located about 100 miles southwest of Anchorage, Redoubt's last eruption occurred in 1989-1990, causing widespread mudfalls and coated Anchorage and other nearby areas with ash. The ash affected air traffic as far south as Texas. Redoubt’s 3,108-meter (10,197-foot) peak has been belching steam for several weeks, with seismologists anticipating a possible eruption. Visible evidence of increased volcanic activity appeared at the volcano’s summit from late January through February. Holes appeared in the ice, and streams of melt water cut across the surface of the Drift Glacier on Redoubt’s north flank.The four explosions were recorded at 10:38 pm and 11:02 pm local time on March 22, and then at 2:14 am, 1:39 am and 4:37 am local time on March 23.
An Ashfall Advisory for the Susitna Valley means that all will likely be deposited there, and residents are advised to seal windows and doors, protect electronics and cover air intakes and open water supplies.
rained @ 8:30 PM

The tallest building in Singapore is the Swissotel,near the city hall MRT station.The Vertical Marathon was held there. There are 73 storeys and 1336 steps at Swissôtel The Stamford .
The tallest building in the world is the Taipei 101.Following it is the Petronas Towers 1&2 in Kuala Lumpur.Next,it is the Sears Towers in Chicago.Then,it is the Jin Mao Building in Shanghai.Lastly,it i the Empire State Building in New York.These are the top 5 tallest buildings in the world for now.Even taller buildings are now still under construction.
rained @ 8:08 AM
Chemistry(often called chim-mystery)
Inoraganic
-elements
-periodic table
Organic
-Usually related to biology
-polymers
-drugs
-perfumes
-alcohols
Physical
-rate of reaction
-heat
Computational
Spectrometry
Analytical
Sports science
-diet
-apparels
-physical
-mental skills
rained @ 5:37 AM

Why some houses are painted white,but their door and window frames are black
The house can reflect the heat when the weather is hot to keep cool and the window and door frames absorb heat.However,when it is cold at night,the the black door and window frames radiate the heat so as to keep warm.
But the heat is also being radiated outside the house,instead of only into the house.Is there a way to prevent that?
rained @ 7:04 AM

Why is the freezer always(usually) on the top of the refridgerator?
The cold air sinks and the hot air rises.The hot air rises and 'goes' from the back of the freezer
into the freezer and the hot air becomes cold air.The cold air comes out and sinks when you open the freezer.That is why you can feel a gush of cold air on your face when you open the freeezer.
rained @ 6:55 AM